Ti/MnO2/PbO2电极的制备及电催化降解罗丹明B

采用电沉积法制备了Ti／MnO2／PbO2电极，并用其对质量浓度为20mg／L的罗丹明B模拟废水进行了电催化降解实验。实验结果表明：原水pH为4．95，无须调节废水的pH；最佳电解实验条件为：支持电解质NazSO4浓度0．09mol／L，电解电流密度40mA／cm^2，处理时间40min，在此条件下罗丹明B的去除率接近100％。     

A directional passive air sampler for monitoring polycyclic aromatic hydrocarbons (PAHs) in air mass

A passive air sampler was developed for collecting polycyclic aromatic hydrocarbons (PAHs) in air mass from various directions. The airflow velocity within the sampler was assessed for its responses to ambient wind speed and direction. The sampler was examined for trapped particles, evaluated quantitatively for influence of airflow velocity and temperature on PAH uptake, examined for PAH uptake kinetics, calibrated against active sampling, and finally tested in the field. The airflow volume passing the sampler was linearly proportional to ambient wind speed and sensitive to wind direction. The uptake rate for an individual PAH was a function of airflow velocity, temperature and the octanol-air partitioning coefficient of the PAH. For all PAHs with more than two rings, the passive sampler operated in a linear uptake phase for three weeks. Different PAH concentrations were obtained in air masses from different directions in the field test.     

应用陶粒过滤-陶瓷膜组合对止咳糖浆制药废水深度处理的试验研究

止咳精浆制药废水经生物接触氧化一体化废水处理装置处理后,其出水中COD、BOD和氨氮等主要污染物质均不能达标排放.在实验室中采用陶粒过滤-陶瓷膜组合对经一体化处理装置处理后的制药废水进行深度处理,在陶粒柱反应器选用粒径为1～2 mm的陶粒滤料,陶瓷膜反应器选用孔径为2～3/μm陶瓷膜的条件下对水样进行测试.废水经陶粒过滤-陶瓷膜组合处理后,其BOD、COD、SS和氨氮指标均可稳定达标排放.     

Temporal and spatial distributions of sediment total organic carbon in an estuary river

Understanding temporal and spatial distributions of naturally occurring total organic carbon (TOC) in sediments is critical because TOC is an important feature of surface water quality. This study investigated temporal and spatial distributions of sediment TOC and its relationships to sediment contaminants in the Cedar and Ortega Rivers, Florida, USA, using three-dimensional kriging analysis and field measurement. Analysis of field data showed that large temporal changes in sediment TOC concentrations occurred in the rivers, which reflected changes in the characteristics and magnitude of inputs into the rivers during approximately the last 100 yr. The average concentration of TOC in sediments from the Cedar and Ortega Rivers was 12.7% with a maximum of 22.6% and a minimum of 2.3%. In general, more TOC accumulated at the upper 1.0 m of the sediment in the southern part of the Ortega River although the TOC sedimentation varied with locations and depths. In contrast, high concentrations of sediment contaminants, that is, total polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), were found in sediments from the Cedar River. There was no correlation between TOC and PAHs or PCBs in these river sediments. This finding is in contradiction to some other studies which reported that the sorption of hydrocarbons is highly related to the organic matter content of sediments. This discrepancy occurred because of the differences in TOC and hydrocarbon source input locations. It was found that more TOC loaded into the southern part of the Ortega River, while almost all of the hydrocarbons entered into the Cedar River. This study suggested that the locations of their input sources as well as the land use patterns should also be considered when relating hydrocarbons to sediment TOC.     

Pattern Classification and Recognition of Invertebrate Functional Groups Using Self-Organizing Neural Networks

Self-organizing neural networks can be used to mimic non-linear systems. The main objective of this study is to make pattern classification and recognition on sampling information using two self-organizing neural network models. Invertebrate functional groups sampled in the irrigated rice field were classified and recognized using one-dimensional self-organizing map and self-organizing competitive learning neural networks. Comparisons between neural network models, distance (similarity) measures, and number of neurons were conducted. The results showed that self-organizing map and self-organizing competitive learning neural network models were effective in pattern classification and recognition of sampling information. Overall the performance of one-dimensional self-organizing map neural network was better than self-organizing competitive learning neural network. The number of neurons could determine the number of classes in the classification. Different neural network models with various distance (similarity) measures yielded similar classifications. Some differences, dependent upon the specific network structure, would be found. The pattern of an unrecognized functional group was recognized with the self-organizing neural network. A relative consistent classification indicated that the following invertebrate functional groups, terrestrial blood sucker; terrestrial flyer; tourist (nonpredatory species with no known functional role other than as prey in ecosystem); gall former; collector (gather, deposit feeder); predator and parasitoid; leaf miner; idiobiont (acarine ectoparasitoid), were classified into the same group, and the following invertebrate functional groups, external plant feeder; terrestrial crawler, walker, jumper or hunter; neustonic (water surface) swimmer (semi-aquatic), were classified into another group. It was concluded that reliable conclusions could be drawn from comparisons of different neural network models that use different distance (similarity) measures. Results with the larger consistency will be more reliable.     

压力式接触氧化法同步硝化反硝化脱氮性能研究

研究了压力式接触氧化法的脱氮性能,分析了容积负荷、溶解氧和停留时间等因素对反应器脱氮效果的影响.研究表明,压力式接触氧化法具有明显的同步硝化反硝化现象,当HRT=1.8 h时,DO高达5.4 mg/L,可获得90%以上的反硝化率.当HRT=1.8 h,溶解氧4～5 mg/L,容积负荷为10～12 kg COD/(m3·d)时,氨氮去除率80%左右,总氮去除率达70%～80%.     

Modification of ferrite–manganese oxide sorbent by doping with cerium oxide

Fe–Mn oxide and Ce-doped Fe–Mn oxide sorbents were studied on the structural and desulfurization behavior in COS removal from syngas. The effects of cerium oxide on the Fe–Mn oxides have been investigated by XRD, BET, TPR, XPS and TEM methods. Analysis data show that the Ce-doped sorbent has larger specific surface area and better particles’ dispersion compared with non-modified Fe–Mn sorbent. The addition of Ce improves the reduction performance of Fe–Mn species. The desulfurization experiments show that the desulfurization activity of sorbent can be increased because of the promotion of the structural and redox properties by ceria doped. The Ce-doped sorbent can reduce COS from 15,000 ppmv to less than 0.1 ppmv at 325 °C and a space velocity of 1000 h⁻¹.     

胺丙基硅的微结构和表面特性在其对两种微囊藻毒素吸附中的作用

考察了粒状胺丙基硅(CUNAX00X)对水溶液中微囊藻毒素-LR(mLR)和微囊藻毒素-LA(mLA)的等温吸附行为,并通过对胺丙基硅结构中的微孔尺寸分布特征、表面官能团--胺丙基团(-CH2CH2CH2NH 3)和羟基自由基(·OH)的红外分析,对吸附机制进行了初步探讨.结果表明,胺丙基硅通过物理吸附和化学吸附对水溶液中的mLR和mLA进行吸附,即胺丙基硅结构中的有效吸附微孔对mLR/mLA的物理吸附,固体表面离子化的胺丙基团和·OH与mLR/mLA分子结构中离子化的羧基(-COO-)以及pH=4.33条件下mLR分子结构中离子化的胍基(-NHCNH·NH 2)之间的弱离子吸附.     

用次磷酸钠废渣制备饲料级磷酸三钙

采用高温煅烧工艺，以工业生产次磷酸钠的废渣为原料，制备饲料级磷酸三钙，并对最佳工艺条件进行探讨。最佳工艺条件：煅烧温度600℃、煅烧时间20min。制得的饲料级磷酸三钙中磷的质量分数为16％～18％，符合Q／YHY01—2003《饲料级磷酸三钙》产品质量企业标准。